JEE Main 2025 Apr 3 Shift 2 — Question Paper

Let $A = \{-2, -1, 0, 1, 2, 3\}$. Let R be a relation on $A$ defined by $x\mathrm{R}y$ if and only if $y = \max\{x, 1\}$. Let $l$ be the number of elements in R. Let $m$ and $n$ be the minimum number of elements required to be added in R to make it reflexive and symmetric relations, respectively. Then $l + m + n$ is equal to

If the domain of the function $f(x) = \log_7 (1 - \log_4 (x^2 - 9x + 18))$ is $(\alpha, \beta) \cup (\gamma, \delta)$, then $\alpha + \beta + \gamma + \delta$ is equal to

Let $f$ be a function such that $f(x) + 3f\left(\dfrac{24}{x}\right) = 4x,\ x \neq 0$. Then $f(3) + f(8)$ is equal to

Let the equation $x(x + 2)(12 - k) = 2$ have equal roots. Then the distance of the point $\left(k, \dfrac{k}{2}\right)$ from the line $3x + 4y + 5 = 0$ is

If $z_1, z_2, z_3 \in \mathbb{C}$ are the vertices of an equilateral triangle, whose centroid is $z_0$, then $\displaystyle\sum_{k=1}^{3} (z_k - z_0)^2$ is equal to

The sum $1 + \dfrac{1+3}{2!} + \dfrac{1+3+5}{3!} + \dfrac{1+3+5+7}{4!} + \ldots$ upto $\infty$ terms, is equal to

Line $\mathrm{L}_1$ of slope 2 and line $\mathrm{L}_2$ of slope $\dfrac{1}{2}$ intersect at the origin O. In the first quadrant, $\mathrm{P}_1, \mathrm{P}_2, \ldots, \mathrm{P}_{12}$ are 12 points on line $\mathrm{L}_1$ and $\mathrm{Q}_1, \mathrm{Q}_2, \ldots, \mathrm{Q}_9$ are 9 points on line $\mathrm{L}_2$. Then the total number of triangles, that can be formed having vertices at three of the 22 points O, $\mathrm{P}_1, \mathrm{P}_2, \ldots, \mathrm{P}_{12}$, $\mathrm{Q}_1, \mathrm{Q}_2, \ldots, \mathrm{Q}_9$, is:

If the probability that the random variable $X$ takes the value $x$ is given by $P(X = x) = k(x + 1)3^{-x},\ x = 0, 1, 2, 3\ldots$, where $k$ is a constant, then $P(X \geq 3)$ is equal to

Let the Mean and Variance of five observations $x_1 = 1,\ x_2 = 3,\ x_3 = a,\ x_4 = 7$ and $x_5 = \mathrm{b}$, $a > \mathrm{b}$, be 5 and 10 respectively. Then the Variance of the observations $n + x_n,\ n = 1, 2, \ldots, 5$ is

Consider the lines $x(3\lambda + 1) + y(7\lambda + 2) = 17\lambda + 5$, $\lambda$ being a parameter, all passing through a point P. One of these lines (say $L$) is farthest from the origin. If the distance of $L$ from the point $(3, 6)$ is $d$, then the value of $d^2$ is

If the four distinct points $(4, 6)$, $(-1, 5)$, $(0, 0)$ and $(k, 3k)$ lie on a circle of radius $r$, then $10k + r^2$ is equal to

Let $C$ be the circle of minimum area enclosing the ellipse $E : \dfrac{x^2}{a^2} + \dfrac{y^2}{b^2} = 1$ with eccentricity $\dfrac{1}{2}$ and foci $(\pm 2, 0)$. Let $PQR$ be a variable triangle, whose vertex $P$ is on the circle $C$ and the side $QR$ of length $2a$ is parallel to the major axis of $E$ and contains the point of intersection of $E$ with the negative $y$-axis. Then the maximum area of the triangle $PQR$ is :

The number of solutions of the equation $\left(4 - \sqrt{3}\right)\sin x - 2\sqrt{3}\cos^2 x = -\dfrac{4}{1 + \sqrt{3}}$, $x \in \left[-2\pi, \dfrac{5\pi}{2}\right]$ is

Each of the angles $\beta$ and $\gamma$ that a given line makes with the positive $y$- and $z$-axes, respectively, is half of the angle that this line makes with the positive $x$-axes. Then the sum of all possible values of the angle $\beta$ is

The distance of the point $(7, 10, 11)$ from the line $\dfrac{x - 4}{1} = \dfrac{y - 4}{0} = \dfrac{z - 2}{3}$ along the line $\dfrac{x - 9}{2} = \dfrac{y - 13}{3} = \dfrac{z - 17}{6}$ is

Let $f : \mathrm{R} \to \mathrm{R}$ be a function defined by $f(x) = \big|\,|x + 2| - 2|x|\,\big|$. If $m$ is the number of points of local minima and $n$ is the number of points of local maxima of $f$, then $m + n$ is

The shortest distance between the curves $y^2 = 8x$ and $x^2 + y^2 + 12y + 35 = 0$ is:

The integral $\displaystyle\int_0^{\pi} \dfrac{8x\,dx}{4\cos^2 x + \sin^2 x}$ is equal to

The area of the region $\left\{(x, y) : |x - y| \leq y \leq 4\sqrt{x}\right\}$ is

Let $y = y(x)$ be the solution of the differential equation $\dfrac{dy}{dx} + 3\left(\tan^2 x\right)y + 3y = \sec^2 x$, $y(0) = \dfrac{1}{3} + e^3$. Then $y\left(\dfrac{\pi}{4}\right)$ is equal to

Let $(1 + x + x^2)^{10} = a_0 + a_1 x + a_2 x^2 + \ldots + a_{20} x^{20}$. If $(a_1 + a_3 + a_5 + \ldots + a_{19}) - 11a_2 = 121k$, then $k$ is equal to ____________.

Let I be the identity matrix of order $3 \times 3$ and for the matrix $\mathrm{A} = \begin{bmatrix} \lambda & 2 & 3 \\ 4 & 5 & 6 \\ 7 & -1 & 2 \end{bmatrix}$, $|\mathrm{A}| = -1$. Let $B$ be the inverse of the matrix $adj\left(A\, adj\left(A^2\right)\right)$. Then $|(\lambda \mathrm{B} + \mathrm{I})|$ is equal to ____________

If the equation of the hyperbola with foci $(4, 2)$ and $(8, 2)$ is $3x^2 - y^2 - \alpha x + \beta y + \gamma = 0$, then $\alpha + \beta + \gamma$ is equal to __________.

Let $\vec{a} = \hat{i} + 2\hat{j} + \hat{k}$, $\vec{b} = 3\hat{i} - 3\hat{j} + 3\hat{k}$, $\vec{c} = 2\hat{i} - \hat{j} + 2\hat{k}$ and $\vec{d}$ be a vector such that $\vec{b} \times \vec{d} = \vec{c} \times \vec{d}$ and $\vec{a} \cdot \vec{d} = 4$. Then $\left|\left(\vec{a} \times \vec{d}\right)\right|^2$ is equal to ________.

If $\displaystyle\lim_{x \to 0}\left(\dfrac{\tan x}{x}\right)^{\frac{1}{x^2}} = p$, then $96\log_e p$ is equal to __________

Match the LIST-I with LIST-II

	LIST-I		LIST-II
A.	Boltzmann constant	I.	$\mathrm{ML^2T^{-1}}$
B.	Coefficient of viscosity	II.	$\mathrm{MLT^{-3}K^{-1}}$
C.	Planck's constant	III.	$\mathrm{ML^2T^{-2}K^{-1}}$
D.	Thermal conductivity	IV.	$\mathrm{ML^{-1}T^{-1}}$

Choose the correct answer from the options given below:

A particle is projected with velocity $u$ so that its horizontal range is three times the maximum height attained by it. The horizontal range of the projectile is given as $\frac{nu^2}{25g}$, where value of $n$ is: (Given, '$g$' is the acceleration due to gravity.)

A particle moves along the $x$-axis and has its displacement $x$ varying with time $t$ according to the equation:

$$x = c_0(t^2 - 2) + c(t - 2)^2$$

where $c_0$ and $c$ are constants of appropriate dimensions. Then, which of the following statements is correct?

[Figure: block A (m₁ = 10 kg) moving with velocity v towards block B (m₂ = 5 kg) which has a spring of k = 3000 N/m attached, both on a horizontal surface]

Consider two blocks A and B of masses $m_1 = 10$ kg and $m_2 = 5$ kg that are placed on a frictionless table. The block A moves with a constant speed $v = 3$ m/s towards the block B kept at rest. A spring with spring constant $k = 3000$ N/m is attached with the block B as shown in the figure. After the collision, suppose that the blocks A and B, along with the spring in constant compression state, move together, then the compression in the spring is, (Neglect the mass of the spring)

Two cylindrical vessels of equal cross sectional area of $2\,\mathrm{m^2}$ contain water upto heights 10 m and 6 m, respectively. If the vessels are connected at their bottom then the work done by the force of gravity is (Density of water is $10^3\,\mathrm{kg/m^3}$ and $g = 10\,\mathrm{m/s^2}$)

A block of mass 1 kg, moving along $x$ with speed $v_i = 10$ m/s enters a rough region ranging from $x = 0.1$ m to $x = 1.9$ m. The retarding force acting on the block in this range is $F_r = -kx$ N, with $k = 10$ N/m. Then the final speed of the block as it crosses rough region is.

A solid steel ball of diameter 3.6 mm acquired terminal velocity $2.45 \times 10^{-2}$ m/s while falling under gravity through an oil of density $925\,\mathrm{kg\,m^{-3}}$. Take density of steel as $7825\,\mathrm{kg\,m^{-3}}$ and $g$ as $9.8\,\mathrm{m/s^2}$. The viscosity of the oil in SI unit is

An ideal gas exists in a state with pressure $P_0$, volume $V_0$. It is isothermally expanded to 4 times of its initial volume ($V_0$), then isobarically compressed to its original volume. Finally the system is heated isochorically to bring it to its initial state. The amount of heat exchanged in this process is

Pressure of an ideal gas, contained in a closed vessel, is increased by 0.4% when heated by 1°C. Its initial temperature must be:

In the resonance experiment, two air columns (closed at one end) of 100 cm and 120 cm long, give 15 beats per second when each one is sounding in the respective fundamental modes. The velocity of sound in the air column is:

A magnetic dipole experiences a torque of $80\sqrt{3}$ N m when placed in uniform magnetic field in such a way that dipole moment makes angle of 60° with magnetic field. The potential energy of the dipole is :

An electric bulb rated as 100W-220V is connected to an ac source of rms voltage 220V. The peak value of current through the bulb is :

Using a battery, a 100 pF capacitor is charged to 60 V and then the battery is removed. After that, a second uncharged capacitor is connected to the first capacitor in parallel. If the final voltage across the second capacitor is 20 V, its capacitance is: (in pF)

A motor operating on 100 V draws a current of 1 A. If the efficiency of the motor is 91.6%, then the loss of power in units of cal/s is

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : If Oxygen ion ($\mathrm{O^{-2}}$) and Hydrogen ion ($\mathrm{H^+}$) enter normal to the magnetic field with equal momentum, then the path of $\mathrm{O^{-2}}$ ion has a smaller curvature than that of $\mathrm{H^+}$.

Reason R : A proton with same linear momentum as an electron will form a path of smaller radius of curvature on entering a uniform magnetic field perpendicularly.

In the light of the above statements, choose the correct answer from the options given below

Two monochromatic light beams have intensities in the ratio 1:9. An interference pattern is obtained by these beams. The ratio of the intensities of maximum to minimum is

A monochromatic light of frequency $5 \times 10^{14}$ Hz travelling through air, is incident on a medium of refractive index '2'. Wavelength of the refracted light will be :

Width of one of the two slits in a Young's double slit interference experiment is half of the other slit. The ratio of the maximum to the minimum intensity in the interference pattern is :

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : The Bohr model is applicable to hydrogen and hydrogen-like atoms only.

Reason R : The formulation of Bohr model does not include repulsive force between electrons.

In the light of the above statements, choose the correct answer from the options given below

The truth table corresponding to the circuit given below is :

[Figure: logic circuit — inputs A and B feed an OR gate; the OR gate output and input A feed an AND gate whose output is C]

A physical quantity $C$ is related to four other quantities $p$, $q$, $r$ and $s$ as follows

$$C = \frac{pq^2}{r^3\sqrt{s}}.$$

The percentage errors in the measurement of $p$, $q$, $r$ and $s$ are 1%, 2%, 3% and 2%, respectively. The percentage error in the measurement of $C$ will be __________ %.

The excess pressure inside a soap bubble A in air is half the excess pressure inside another soap bubble B in air. If the volume of the bubble A is $n$ times the volume of the bubble B, then, the value of $n$ is __________.

Two cells of emfs 1 V and 2 V and internal resistances $2\ \Omega$ and $1\ \Omega$, respectively, are connected in series with an external resistance of $6\ \Omega$. The total current in the circuit is $I_1$. Now the same two cells in parallel configuration are connected to same external resistance. In this case, the total current drawn is $I_2$. The value of $\left(\frac{I_1}{I_2}\right)$ is $\frac{x}{3}$. The value of $x$ is __________.

Light from a point source in air falls on a spherical glass surface (refractive index, $\mu = 1.5$ and radius of curvature $= 50$ cm). The image is formed at a distance of 200 cm from the glass surface inside the glass. The magnitude of distance of the light source from the glass surface is __________ m.

An electron in the hydrogen atom initially in the fourth excited state makes a transition to $n^{\text{th}}$ energy state by emitting a photon of energy 2.86 eV. The integer value of n will be __________.

Mass of magnesium required to produce 220 mL of hydrogen gas at STP on reaction with excess of dil. HCl is

Given: Molar mass of Mg is $24\ \mathrm{g\ mol^{-1}}$.

For electrons in '2s' and '2p' orbitals, the orbital angular momentum values, respectively are :

Given below are two statements:

Statement I : When a system containing ice in equilibrium with water (liquid) is heated, heat is absorbed by the system and there is no change in the temperature of the system until whole ice gets melted.

Statement II : At melting point of ice, there is absorption of heat in order to overcome intermolecular forces of attraction within the molecules of water in ice and kinetic energy of molecules is not increased at melting point.

In the light of the above statements, choose the correct answer from the options given below

10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume upto the mark with distilled water. The solution in this flask is :

40 mL of a mixture of $\mathrm{CH_3COOH}$ and HCl (aqueous solution) is titrated against 0.1 M NaOH solution conductometrically. Which of the following statement is correct?

[Figure: conductometric titration curve — Conductance (mS) vs $V_{\mathrm{NaOH}}$/mL; conductance falls from A to a minimum at B (2.0 mL), rises gently from B to C (5.0 mL), then rises steeply from C to D]

The standard cell potential $\left(\mathrm{E^{\ominus}_{cell}}\right)$ of a fuel cell based on the oxidation of methanol in air that has been used to power television relay station is measured as 1.21 V. The standard half cell reduction potential for $\mathrm{O_2}$ $\left(\mathrm{E^{\circ}_{O_2/H_2O}}\right)$ is 1.229 V.

Choose the correct statement:

Consider the following statements related to temperature dependence of rate constants.

Identify the correct statements.

A. The Arrhenius equation holds true only for an elementary homogenous reaction. B. The unit of A is same as that of k in Arrhenius equation. C. At a given temperature, a low activation energy means a fast reaction. D. A and Ea as used in Arrhenius equation depend on temperature. E. When Ea >> RT, A and Ea become interdependent.

Choose the correct answer from the options given below:

Given below are two statements:

Statement I : Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get dried than wet nylon polymer based clothes.

Statement II : Intermolecular hydrogen bonding with water molecule is more in nylon-based clothes than in the case of cotton clothes.

In the light of above statements, choose the correct answer from the options given below

Match the LIST-I with LIST-II

LIST-I (Family)	LIST-II (Symbol of Element)
A. Pnictogen (group 15)	I. Ts
B. Chalcogen	II. Og
C. Halogen	III. Lv
D. Noble gas	IV. Mc

Choose the correct answer from the options given below:

The correct orders among the following are

A. Atomic radius : $\mathrm{B < Al < Ga < In < Tl}$ B. Electronegativity : $\mathrm{Al < Ga < In < Tl < B}$ C. Density : $\mathrm{Tl < In < Ga < Al < B}$ D. 1st Ionisation Energy : $\mathrm{In < Al < Ga < Tl < B}$

Choose the correct answer from the options given below:

Given below are two statements:

Statement I : $\mathrm{CrO_3}$ is a stronger oxidizing agent than $\mathrm{MoO_3}$

Statement II : Cr(VI) is more stable than Mo(VI)

In the light of the above statements, choose the correct answer from the options given below

Identify the diamagnetic octahedral complex ions from below ;

A. $\mathrm{[Mn(CN)_6]^{3-}}$ B. $\mathrm{[Co(NH_3)_6]^{3+}}$ C. $\mathrm{[Fe(CN)_6]^{4-}}$ D. $\mathrm{[Co(H_2O)_3F_3]}$

Choose the correct answer from the options given below:

Compounds that should not be used as primary standards in titrimetric analysis are :

A. $\mathrm{Na_2Cr_2O_7}$ B. Oxalic acid C. NaOH D. $\mathrm{FeSO_4 \cdot 6H_2O}$ E. Sodium tetraborate

Choose the most appropriate answer from the options given below:

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is

(Given : Aqueous tension at 300 K = 15 mm Hg)

Given below are two statements:

Statement I : Hyperconjugation is not a permanent effect.

Statement II : In general, greater the number of alkyl groups attached to a positively charged C-atom, greater is the hyperconjugation interaction and stabilization of the cation.

In the light of the above statements, choose the correct answer from the options given below

What is the correct IUPAC name of [Figure: benzene ring bearing $\mathrm{CO_2H}$, with $\mathrm{OH}$ on the carbon adjacent to $\mathrm{CO_2H}$, $\mathrm{Br}$ on the carbon adjacent to the $\mathrm{OH}$, and $\mathrm{NO_2}$ meta to $\mathrm{CO_2H}$ (positions: 1-$\mathrm{CO_2H}$, 2-$\mathrm{OH}$, 3-$\mathrm{Br}$, 5-$\mathrm{NO_2}$)] ?

In the following series of reactions identify the major products A & B respectively

$$\text{Bromobenzene} \xrightarrow[\mathrm{H_2SO_4}]{\mathrm{SO_3}} \underset{\text{Major product}}{\mathrm{A}} \xrightarrow{\mathrm{Br_2,\ Fe}} \underset{\text{Major product}}{\mathrm{B}}$$

[Figure: bromobenzene structure shown; the options are drawn structures]

The major product (P) in the following reaction is :

$$\mathrm{Ph{-}\overset{\displaystyle O}{\overset{\|}{C}}{-}\overset{\displaystyle O}{\overset{\|}{C}}{-}H} \xrightarrow[\Delta]{\mathrm{KOH}} \underset{\text{Major Product}}{\mathrm{P}}$$

The sequence from the following that would result in giving predominantly 3, 4, 5-Tribromoaniline is :

Fat soluble vitamins are:

A. Vitamin $\mathrm{B_1}$ B. Vitamin C C. Vitamin E D. Vitamin $\mathrm{B_{12}}$ E. Vitamin K

Choose the correct answer from the options given below:

[Figure: P–V diagram; P/atm on the y-axis (1.00 and 3.00 marked), V/cm$^3$ on the x-axis (1000 and 2000 marked); path: point 1 (1.00 atm, 1000 cm$^3$) up to point 2 (3.00 atm, 1000 cm$^3$), right to point 3 (3.00 atm, 2000 cm$^3$), down to point 4 (1.00 atm, 2000 cm$^3$)]

A perfect gas (0.1 mol) having $\overline{C}_v = 1.50\mathrm{R}$ (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is (–) __________ J (nearest integer)

[Given : $\mathrm{R} = 0.082\ \mathrm{L\ atm\ K^{-1}\ mol^{-1}}$]

A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is $5\ \mathrm{kJ\ K^{-1}}$. As a result of combustion reaction, the temperature of the calorimeter is increased by 5 K. The magnitude of the heat of combustion of octane at constant volume is __________ $\mathrm{kJ\ mol^{-1}}$ (nearest integer).

Among, Sc, Mn, Co and Cu, identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is __________ BM (in nearest integer).

X g of nitrobenzene on nitration gave 4.2 g of m-dinitrobenzene. X = __________ g. (nearest integer)

[Given : molar mass (in $\mathrm{g\ mol^{-1}}$) C : 12, H : 1, O : 16, N : 14]

The total number of structural isomers possible for the substituted benzene derivatives with the molecular formula $\mathrm{C_9H_{12}}$ is __________.